Intercomparison of shipboard and moored CARIOCA buoy seawater fCO₂ measurements in the Sargasso Sea     

Nicholas R. Bates  Liliane Merlivat  Laurence Beaumont  A. Christine Pequignet 《Marine Chemistry》2000,72(2-4)

The ocean is an important sink for carbon and heat, yet high-resolution measurements of biogeochemical properties relevant to global climate change are being made only sporadically in the ocean at present. There is a growing need for automated, real-time, long-term measurements of CO₂ in the ocean using a network of sensors, strategically placed on ships, moorings, free-drifting buoys and autonomous remotely operated vehicles. The ground-truthing of new sensor technologies is a vital component of present and future efforts to monitor changes in the ocean carbon cycle and air–sea exchange of CO₂.A comparison of a moored Carbon Interface Ocean Atmosphere (CARIOCA) buoy and shipboard fugacity of CO₂ (fCO₂) measurements was conducted in the western North Atlantic during two extended periods (>1 month) in 1997. The CARIOCA buoy was deployed on the Bermuda Testbed Mooring (BTM), which is located 5 km north of the site of the US Joint Global Ocean Flux Study (JGOFS) Bermuda Atlantic Time-series Study (BATS). The high frequency of sampling revealed that temperature and fCO₂ responded to physical forcing by the atmosphere on timescales from diurnal to 4–8 days. Concurrent with the deployments of the CARIOCA buoy, frequent measurements of surface fCO₂ were made from the R/V Weatherbird II during opportunistic visits to the BTM and BATS sites, providing a direct calibration of the CARIOCA buoy fCO₂ data. Although, the in situ ground-truthing of the CARIOCA buoy was complicated by diurnal processes, sub-mesoscale and fine-scale variability, the CARIOCA buoy fCO₂ data was accurate within 3±6 μatm of shipboard fCO₂ data for periods up to 50 days. Longer-term assessments were not possible due to the CARIOCA buoy breaking free of the BTM and drifting into waters with different fCO₂-temperature properties. Strategies are put forward for future calibration of other in situ sensors.  相似文献   

Organic tracers from biomass burning in atmospheric particulate matter over the ocean     

Bernd R. T. Simoneit  Vladimir O. Elias   《Marine Chemistry》2000,69(3-4)

Particulate matter from the atmosphere over the Atlantic Ocean along the South American and African Continents has been analyzed for organic tracers from natural and biomass burning emissions. The major biomarker compounds characterized are natural products from continental vegetation consisting primarily of epicuticular wax components. For example, n-alkanes ranged from C₂₅ to C₃₅, with an odd carbon number predominance and carbon maxima (C_max) at 29 or 31. Concentrations of n-alkanes varied from 0.3 to 680 ng/m³. Nevertheless, n-alkanols are the dominant terrestrial tracers in almost all samples (concentrations from 0.1 to 780 ng/m³) and ranged from C₂₂ to C₃₄ with an even carbon number predominance. Despite the major presence of the natural tracers, organic components from biomass burning emissions are also present in the particulate matter. The major tracers from this source are thermal degradation products from the biopolymer cellulose, namely the dianhydromonosaccharide derivatives levoglucosan, galactosan, and mannosan. In general, the concentrations of levoglucosan, the major derivative from this source in all samples, varied from 0.0008 to 0.15 ng/m³ in atmospheric samples collected over the ocean and from 0.04 to 4860 ng/m³ in terrestrial particulate matter, used as reference in this study. Dehydroabietic acid, another marker compound emitted from burning of Gymnosperm fuel, is also detectable in most oceanic samples at concentrations ranging from 0.0001 to 0.4 ng/m³, whereas in terrestrial aerosol particulate matter, this component is present at much higher concentrations (0.23–440 ng/m³). The presence of these tracers in atmospheric particulate matter over the ocean confirms the long-range transport of smoke from biomass burning off the continents.  相似文献   

Benthic Disturbance and Impact Experiments in the Central Indian Ocean Basin     

Rahul Sharma  B. Nagendernath  A. B. Valsangkar  G. Parthiban  K. M. Sivakolundu  Gavin Walker 《Marine Georesources & Geotechnology》2000,18(3):209-221

As a part of the Environmental Impact Assessment studies for nodule mining, a long-term program has been initiated in the Central Indian Basin. Multidisciplinary studies on geological, biological, physical, and chemical parameters were carried out in an area selected on the basis of baseline data collected in the first phase of the program. A benthic disturbance was simulated with a hydraulic device also used in the previous experiments in the Pacific Ocean. A site of 3,000 ×200 m was repeatedly disturbed by a combination of fluidizing pump and suction pump to dislodge and discharge sediment from the seafloor into the water column 5 m above the seafloor. During 9 days of operation, 26 tows were carried out for 47 h of disturbance, resuspending about 6,000 m 3 of sediment along an 88-km line. Data for postdisturbance impact assessment were collected with sediment traps, deep-towed cameras, seafloor samples, and conductivity-temperature depth sensor (CTD)-rosette observations. Seafloor data, sediment samples, and water column studies were aimed at evaluating the impact of benthic disturbance, on the basis of pre- and postdisturbance data collected during the experiment. Observations show that vertical mixing of sediment as well as its lateral movement and resedimentation because of plume migration alters various parameters and leads to changes in the environment around the area.  相似文献   

Microscale Response of Sediment Variables to Benthic Disturbance in the Central Indian Ocean Basin     

Shanta Nair  C. Mohandass  P. A. Loka Bharathi  G. Sheelu  Raghukumar Chandralata 《Marine Georesources & Geotechnology》2000,18(3):273-283

The response of sediment bacteria and biochemical variables to benthic disturbance was investigated in the Central Indian Ocean Basin from cores at nine stations. Generally, bacterial density and biochemical variables declined vertically with depth in the upper layers of the cores. Mechanical disturbance caused by a hydraulic disturber brought about a substantial decrease in total bacterial numbers. However, the numbers of retrievable bacteria increased by two orders of magnitude. The biochemical parameters decreased in quantity with a shift in the linear relationship. The data suggest that abiotic artifacts will directly affect the biomass and biochemistry of the sediment.  相似文献   

The effect of diapycnal mixing on the ventilation and CFC-11 uptake in the Southern Ocean     

Yongqi GAO  Helge DRANGE 《大气科学进展》2004,21(5):755-766

1. Introduction Ocean General Circulation Models (OGCMs) arekey tools in the assessment of the future ocean up-take of atmospheric greenhouse gases and heat. Fur-thermore, whereas nature experiences one realisationof the climate state, climate models can be used as alaboratory to produce a multitude of climate realisa-tions, and by that contribute to the understanding ofthe variability and stability properties of the system.It is, in this respect, crucial to evaluate the climatemodels ag…  相似文献   

An ocean of surprises – Trends in human use,unexpected dynamics and governance challenges in areas beyond national jurisdiction     

《Global Environmental Change》2014

The expanse of ocean which makes up all marine areas beyond national jurisdiction has been characterized as the last frontier of exploitation on the planet, a figurative final “Wild West”. Existing users of areas beyond national jurisdiction, with the exception of fisheries, currently have a limited footprint there as a consequence, in part, of substantial hurdles in technological development that need to be overcome before many resources can be extracted at a commercially viable scale. However, we argue surprise shifts perpetuated by both established and emerging users could lead to an expansion in actors taking opportunities to chase lucrative resources that they are currently constrained from exploiting. Rapid development could also lead to a “crowded ocean” due to the multiplication of users which could present a problem given the current lack of a unified institutional framework for governance connecting the different user groups. Here, we have collated trends in human use of areas beyond national jurisdiction and offer a framework for, and examples of, unexpected dynamics relevant to living and non-living marine resources. Such an approach is necessary in order to begin to mobilize an adequate governance response to changing conditions and uses of areas beyond national jurisdiction. This governance response must be able to govern established or potential users, be flexible and adaptive in response to unexpected and unpredictable dynamics and be able to transform in the face of unpredictable future uses of this vast area. Here we present a set of institutional design principles as a first tentative step in this direction.  相似文献   

南印度洋偶极子的特征及其与ENSO的关系          下载免费PDF全文

张岚  杜岩  张玉红  徐海明 《大气科学学报》2014,37(6):695-704

利用逐月OISST、ERSST及NCEP2表面风场等资料探讨了南印度洋偶极子(Southern Indian Ocean Dipole,SIOD)的结构特征、形成原因及其与ENSO的关系。结果表明:在南印度洋,偶极子形态的年际海表面温度异常在10—12月出现,次年2月达到极值,随后的4—6月消亡。SIOD的形成主要是风场、潜热通量和短波辐射通量起作用,混合层深度异常加厚或变浅有助于SIOD的形成。近30 a资料表明,SIOD的盛期超前ENSO 9~10个月,且具有季节锁相特征。20世纪70年代中期发生年代际气候突变后,SIOD与ENSO的相关关系显著增强。正SIOD事件之后一般都有El Nio事件发生,负SIOD事件之后都有La Nia事件发生。  相似文献   

Tides and Wind-Driven Circulation in the Tropical and Southern Atlantic Ocean:The BRAZCOAST System          下载免费PDF全文

Ricardo de CAMARGO  Joseph HARARI 《大气和海洋科学快报》2014,(5):476-480

The Brazilian coast is characterized by dif- ferent tidal regimes and distinct meteorological influ- ences. The northern part has larger tidal amplitudes and is permanently affected by trade winds and tropical distur- bances; the southern portion has smaller tidal amplitudes and is frequently influenced by extratropical cyclone ac- tivity. Besides these aspects, many features regarding current structure and behavior are also present, such as the equatorial system of currents, the subtropical gyre and the corresponding western boundary currents, and the Bra- zil-Malvinas confluence region. Within this context, ef- forts were made to develop the BRAZCOAST system, capable of describing the processes that determine the oceanic circulation from large to coastal scales. A cus- tomized version of the Princeton Ocean Model （POM） was implemented in a basin-scale domain covering the whole of the tropical and southern Atlantic Ocean, with 0.5° spatial resolution, as well as three nested grids with （1/12）° resolution covering the different parts of the Bra- zilian shelf, in a one-way procedure. POM was modified to include tidal potential generator terms and a par- tially-clamped boundary condition for tidal elevations. The coarse grid captured large-scale features, while the nested grids detailed local circulations affected by bathymetry and coastal restrictions. An interesting aspect at the coarse grid level was the relevance of the Weddell Sea to the location of the tidal amphidromic systems.  相似文献   

Interdecadal and Interannnual Variabilities of the Antarctic Oscillation Simulated by CAM3          下载免费PDF全文

XUE Feng  SUN Dan  ZHOU Tian-Jun 《大气和海洋科学快报》2014,7(6):515-520

Based on four sets of numerical simulations prescribed with atmospheric radiative forcing and sea surface temperature（SST） forcing in the Community Atmospheric Model version 3（CAM3）, the interannual and interdecadal variabilities of the Antarctic oscillation（AAO） during austral summer were studied. It was found that the interannual variability is mainly driven by SST forcing. On the other hand, atmospheric radiative forcing plays a major role in the interdecadal variability. A cooling trend was found in the high latitudes of the Southern Hemisphere（SH） when atmospheric radiative forcing was specified in the model. This cooling trend tended to enhance the temperature gradient between the mid and high latitudes in the SH, inducing a transition of the AAO from a negative to a positive phase on the interdecadal timescale. The cooling trend was also partly weakened by the SST forcing, leading to a better simulation compared with the purely atmospheric radiative forcing run. Therefore, SST forcing cannot be ignored, although it is not as important as atmospheric radiative forcing.  相似文献   

Response of benthic opportunistic polychaetes and amphipods index to different perturbations in coastal oligotrophic areas (Canary archipelago,North East Atlantic Ocean)     

Rodrigo Riera  Jose Antonio de‐la‐Ossa‐Carretero 《Marine Ecology》2014,35(3):354-366

Oligotrophic areas harbour low macrofaunal abundance and patchy distribution. In these areas it is necessary to test the reliability of biological indicators, especially those based on taxonomic sufficiency where the level of identification is balanced against the need for ecological information and could affect the efficiency of bioindicators. The BOPA (benthic opportunistic polychaetes and amphipods) index was applied in five coastal areas subjected to different perturbations (aquaculture, harbour, brine, sewage, and thermal pollution) in the Canary archipelago, an oligotrophic area of the Atlantic Ocean. Significant differences in the BOPA index between impact and control sites were only found in the area affected by a harbour. Perturbations such as aquaculture, brine or sewage discharge produce only a weak response of the BOPA index, whereas no effects were observed at thermal pollution‐impacted locations. The BOPA index should be used with caution to establish the ecological status of coastal water bodies in the Canary Islands, since it was only reliable in strongly impacted regions (enlargement harbour works), but did not respond clearly to other man‐induced perturbations.  相似文献